| Unlockable: | How to Unlock: |
| Diao Chen | Successfully complete Si Shui Gate (Dong Zhoug's side) 100% in Free mode to unlock Diao Chen. |
| Dong Zhoug | Successfully complete Si Shui Gate 100% in Musou mode to unlock Dong Zhoug. |
| Guan Ping | Clear Zhao Yun mosou mode |
| Hex Mark horse | Defeat Liu Bei in Si Shui Gate with Dong Zhoug to unlock the Hex Mark horse. |
| Houng Zhong | Clear Zhao Yun mosou mode |
| Jiang Wei | Successfully complete Musou mode with Zhauge Liang to unlock Jiang Wei. |
| Liu Bei | Successfully complete the last stage in the fourth column in Musou mode with Shu to unlock Liu Bei. |
| Lu Bu | Successfully complete the Battle Of Xia Pi (Dong Zhoug's side) 100% in Free mode to unlock Lu Bu. |
| Meng Hou | Successfully complete the Nan Zhong stage 100% in Conquest mode to unlock Meng Hou. |
| Pong Tong | Successfully complete the last stage in the fourth column in Musou mode with Shu to unlock Pong Tong. |
| Red Hare horse | Defeat Guan Yu in Escape Chang Ban Battle with the Yellow Turban force to unlock the Red Hare horse. |
| Shadow horse | Defeat Cao Cao in the Battle Of Wan Castle to unlock the Shadow horse. |
| Storm horse | Defeat Cao Cao in the Battle Of Xia Pi with the Dong Zhoug force to unlock the Storm horse. |
| Yue Ying | Successfully complete Musou mode with Zhauge Liang to unlock Yue Ying. |
| Zhang Jiao | Successfully complete the Yellow Turban stage 100% to unlock Zhang Jiao. |
| Zhauge iang | Clear Zhao Yun mosou mode |
| Zhauge Lang | Successfully complete Musou mode with Zhao Yun to unlock Zhauge Lang. |
